Leave Your Message
Products Categories
Featured Products

Rubidium Chloride (RbCl) - High-Quality Suppliers and Factory in China for Alkali Metal Halides

Product Overview
Rubidium chloride (RbCl) is a prominent alkali metal halide featuring the chemical formula RbCl and an impressive molecular weight of 120.92 g/mol. This compound is characterized by its colorless cubic crystal structure, belonging to the space group Fm3m, similar to that of NaCl, with a lattice parameter of a = 6.581 Å. RbCl exhibits remarkable thermal stability with a melting point of 715 °C and a boiling point reaching 1390 °C. The density of Rubidium chloride is 2.80 g/cm³, and it is notably soluble in water, with a solubility of 77 g per 100 mL at 25 °C. Its aqueous solution is neutral and demonstrates high ionic conductivity, making it a valuable material in various applications. As one of the leading suppliers and manufacturers in China, our factory ensures high-quality Rubidium chloride to meet diverse industrial needs.

    Spectral and Thermodynamic Properties

    RbCl exhibits typical ionic bond vibration modes in the infrared spectrum, and its phonon spectrum shows a characteristic absorption peak at ~200 cm⁻¹. In terms of thermodynamic data, the standard enthalpy of formation (ΔfH°) is -430.5 kJ/mol, and the entropy (S°) is 95.9 J/(mol·K). The band structure of RbCl shows that its band gap is about 8.4 eV, which is a typical insulator, but it can exhibit significant ion migration behavior under high temperature or electric field, making it one of the candidate materials for solid electrolyte research.

    Chemical Behavior

    The chemical properties of RbCl are similar to those of NaCl and KCl, but because the Rb⁺ ion radius is larger (1.52 Å), its lattice energy is slightly lower (~659 kJ/mol). RbCl can react with sulfuric acid to form Rb₂SO₄, or react with AgNO₃ to form AgCl precipitate. At high temperature, RbCl can participate in solid phase reaction to synthesize composite oxides (such as RbTaO₃). It is worth noting that RbCl exhibits a purple-red color in flames (Rb characteristic emission line ~780 nm), and is often used for atomic absorption spectroscopy (AAS) calibration.

    Main Application Areas

    Radioactive Tracers
    ⁸²RbCl (half-life 1.27 min) is a commonly used positron emitter for PET myocardial perfusion imaging, prepared by a ⁸²Sr/⁸²Rb generator, and used for coronary heart disease diagnosis.
    Solid Electrolytes
    RbCl-doped glass-ceramic systems (such as RbCl-Al₂O₃) have an ionic conductivity of up to 10⁻³ S/cm at moderate temperatures (300-500 °C), which is suitable for solid-state battery research.
    Optical Materials
    RbCl single crystals can be used for infrared optical windows (transmittance range ~0.2-25 μm), and as a matrix material doped with rare earth ions (such as RbCl:Eu²⁺) to prepare scintillators.
    Molecular Biology
    Rb⁺ can replace K⁺ to participate in enzymatic reactions and is used to study the kinetic mechanism of ion channels (such as Na⁺/K⁺-ATPase).

    Safety and Storage

    RbCl has low toxicity (LD₅₀ rat oral administration is about 4440 mg/kg), but high concentrations of Rb⁺ may interfere with K⁺ metabolism in organisms. Storage needs to be protected from light and moisture because it is easy to absorb moisture and agglomerate. It is recommended to wear protective equipment during experimental operations to avoid dust inhalation.

    Conclusion

    As a basic compound of rubidium chemistry, RbCl has important value in energy materials, nuclear medicine, and spectral analysis. Its unique ion migration characteristics and biocompatibility provide potential research directions for the development of future solid-state batteries and integrated diagnosis and treatment technologies.

    Frequently Asked Questions (FAQ)

    Q: What are the key thermodynamic properties of Rubidium Chloride?
    Rubidium Chloride (RbCl) has a standard enthalpy of formation (ΔfH°) of -430.5 kJ/mol and a standard entropy (S°) of 95.9 J/(mol·K). Its band structure reveals a band gap of approximately 8.4 eV, classifying it as an insulator.
    Q: How does RbCl behave chemically compared to other alkali metal chlorides?
    RbCl exhibits chemical properties similar to NaCl and KCl. However, due to the larger radius of the Rb⁺ ion (1.52 Å), its lattice energy is slightly lower at around 659 kJ/mol. It reacts with sulfuric acid to yield Rb₂SO₄ and with silver nitrate to form AgCl precipitate.
    Q: What role does RbCl play in medical imaging?
    The isotope ⁸²RbCl serves as a positron emitter with a short half-life of 1.27 minutes. It is generated via a ⁸²Sr/⁸²Rb generator and is widely used as a radioactive tracer in PET myocardial perfusion imaging to diagnose coronary heart disease.
    Q: Can Rubidium Chloride be used in energy storage applications?
    Yes. When doped into glass-ceramic systems (such as RbCl-Al₂O₃), RbCl shows an ionic conductivity of up to 10⁻³ S/cm at moderate temperatures (300-500 °C), making it a candidate material for solid-state electrolyte and battery research.
    Q: What are the safety and storage requirements for RbCl?
    RbCl has low toxicity, with an oral LD₅₀ in rats of approximately 4440 mg/kg. However, high concentrations can interfere with potassium metabolism. It must be stored away from light and moisture to prevent agglomeration, and operators should wear protective gear to prevent dust inhalation.

    Leave Your Message